I used pitchers as pinch hitters last year with good results. Here's the scoop:
Only pitchers in the starting rotation will pinch hit, your bullpen will not PH. If they have low stamina while resting between starts then they wont make good pinch hitters. so put your hitting pitchers at the back end of your rotation and draft enough innings.
All of your bench players must be on rest. you must give up your bench, no defensive replacements no resting players in a blowout. players on rest will not PH even if your pitchers are used up.
Pitchers will only pinch hit for other pitchers, they wont PH for a weaker hitting position player.
This is a cumbersome strategy. I liked it when good hitting pitchers were a bargain. I dont recommend it now that their salaries have gone up. also not recommended if you have just one hitting pitcher, you really need several or else it's not worth the trouble.